So I want to know what's the defination of the center of gravity in Orbiter or what should I do to find the coordinate of the grabity center?
The centre of gravity is always {0,0,0} in local vessel coordinates. If you want to avoid a thruster making angular accelerations the thruster must act through that point or have a pair (or more) of thrusters so that their torque balances out. For example, these would be OK:
1. Thruster attack point {0,0,-2}, thruster direction {0,0,1}.
2. Thruster attack points {-1,0,-2},{1,0,-2}, thruster direction {0,0,1}.