Are you talking about Atlas V?
IIRC, they actually throttle back for max Q, thus they hit later than you would expect from full thrust curve alone.
Plus, they may use a different gravity turn, etc.
Well, according to the user guide, the 401 maintains full throttle until 100 seconds, which is after both mach 1 and max Q, then it throttles back to 95% for the rest of the burn until the g limits throttle it back more. It's the one's with SRB's that throttle back through that period.
Interestingly, I was wrong about the Max Q. it's close to dead on time wise. though a bit lower in altitude and higher in pressure difference.
The other factor I failed to consider until just now though is payload, The one I'm using is on the light side, I need to play with that as well as possibly the timing of the gravity turn to see if I can't match up with their "generic" GTO launch profile.