The easiest way to do that would probably be to nuke the ice caps so a lot of the CO2 and water ice melt and thicken the atmosphere.
But still, you're lacking *a lot* of nitrogen. Keep in mind that Earth's atmosphere is only ~21% O2... mostly it's nitrogen. Where do you get such huge quantities of nitrogen on Mars?
Humans die from too much oxygen, just the same as having too little of it. And just for the record, no you cannot use CO2 to bring down the ratio of Oxygen in the atmosphere. CO2 is... well, kinda toxic.
If we could go to Mars, we would have been there by now.
What resources? Just because we found water doesn't mean we can just instantly turn the planet into something that's gonna support human life.
Not to mention that most of that water would probably be used to thicken the atmosphere to the extent where humans can survive.
If you wanna have people there, you've got to have plants. What exactly is gonna grow on Mars?
Mars would be able to support a small population - a scientific outpost, relying on machines to make air, water, pressure, handle waste,... but that sort of life just isn't feasible for large populations.