How are the dry (empty) masses determined?
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There is also a first order estimate formula based on crew size and mission duration. The masses calculated by that are a bit on the heavy side, but give you pretty useful numbers for the start.
[math]M_{Initial, Dry} = 592 \times (N_{crew} \times T_{mission} \lbrack d \rbrack \times V_{pressurized} \lbrack m^3 \rbrack)^{0.346}[/math]
Source?